155mm固定翼双旋弹二维弹道修正引信的翼面转速特性及修正能力研究

二维弹道修正引信实现弹道修正的前提是对头部翼面部分转速进行控制。基于155 mm 固定翼双旋弹二维弹道修正引信平台,分别对双旋环境下弹体和翼面的转速特性进行了分析。建立翼面作用下双旋弹丸运动模型,采用计算流体力学软件对二维弹道修正引信进行数值模拟,计算得到了翼面各项气动力参数;通过对二维弹道修正滚转通道动力学方程展开分析,以弹丸和头部翼面部分转动惯量为基础,综合分析了翼面转动惯量、摩擦力矩、翼面滚转阻尼力矩和翼面导转力矩对全弹道转速、落点、横向偏差、攻角的影响;在转速控制基础上对155 mm 固定翼二维弹道修正引信修正能力进行了评估。研究结果表明：二维弹道修正引信导转翼面角度取5.0°~5.5°、修正翼面角度取8°~9°时可以满足控制所需的平衡转速和修正能力要求;双旋转速仿真结果可以反映弹道修正引信、精确制导组件等双旋弹丸的转速特性,为此类双旋弹丸翼面部分设计提供了理论依据。     

高速钢淬火脱碳的检测与控制

针对单纯用化验盐浴中氧化钡含量的方法检查高速钢盐浴淬火脱碳的情况,介绍了在高速钢工具生产中应用的钢箔法检测脱碳和根据钢箔法开发的脱碳检测仪。同时还介绍了可以清晰显示高速钢脱碳层的两种金相法和显微硬度压痕法。     

硅钼蓝分光光度法测定高铍铍铝合金中硅

高铍铍铝合金中的杂质元素硅对高铍铍铝合金热等静压、精密铸造及耐腐蚀性能影响较大,需要对其含量进行严格控制,所以测定高铍铍铝合金中的硅具有重要意义。采用硫酸(1+1)、硝酸和氢氟酸于水浴条件下溶解试样,用硼酸掩蔽剩余氟离子,在0.10~0.15mol/L硫硝混酸介质下,钼酸铵与硅反应生成硅钼黄杂多酸,稳定20min后,用草酸掩蔽铁离子,同时加入抗坏血酸将硅钼黄还原成硅钼蓝,放置10min,于波长820nm处采用分光光度法进行测定,实现了硅钼蓝分光光度法对高铍铍铝合金(铍的质量分数为60%~70%)中硅的测定。在优化的实验条件下,试液中硅质量在10~60μg范围内与其对应的吸光度呈良好的线性关系,相关系数为1.000,方法中硅的检出限和测定下限分别为0.0021%(质量分数,下同)和0.0071%。按照实验方法测定60BeAl和70BeAl两个高铍铍铝合金试样中硅含量,测得结果的相对标准偏差(RSD,n=8)为2.9%~3.4%。将实验方法用于测定高铍铍铝合金实际试样中硅含量,结果与电感耦合等离子体原子发射光谱法(ICP-AES)相吻合。     

Improvement of quantitative analysis of molybdenum element using PLS-based approaches for laser-induced breakdown spectroscopy in various pressure environments

An experimental setup has been designed and realized in order to optimize the characteristics of laser-induced breakdown spectroscopy system working in various pressure environments. An approach combined the normalization methods with the partial least squares(PLS) method are developed for quantitative analysis of molybdenum(Mo) element in the multi-component alloy,which is the first wall material in the Experimental Advanced Superconducting Tokamak. In this study, the different spectral normalization methods(total spectral area normalization,background normalization, and reference line normalization) are investigated for reducing the uncertainty and improving the accuracy of spectral measurement. The results indicates that the approach of PLS based on inter-element interference is significantly better than the conventional PLS methods as well as the univariate linear methods in the various pressure for molybdenum element analysis.     

Masking the Peroxidase-Like Activity of the Molybdenum Disulfide Nanozyme Enables Label-Free Lipase Detection

Two-dimensional MoS₂ nanoparticles (2D-nps) exhibit artificial enzyme properties that can be regulated at bio-nanointerfaces. We discovered that protein lipase is able to tune the peroxidase-like activity of MoS₂ 2D-nps, offering low-nanomolar, label-free detection and identification in samples with unknown identity. The inhibition of the peroxidase-like activity of the MoS₂ 2D-nps was demonstrated to be concentration dependent, and as low as 5 nm lipase was detected with this approach. The results were compared with those obtained with several other proteins that did not display any significant interference with the nanozyme behavior of the MoS₂ 2D-nps. This unique response of lipase was characterized and exploited for the successful identification of lipase in six unknown samples by using qualitative visual inspection and a quantitative statistical analysis method. The developed methodology in this approach is noteworthy for many aspects; MoS₂ 2D-nps are neither labeled with a signaling moiety nor modified with any ligands for signal readout. Only the intrinsic nanozyme activity of the MoS₂ 2D-nps is exploited for this detection approach. No analytical equipment is necessary for the visual detection of lipase. The synthesis of the water-soluble MoS₂ 2D-nps is low costing and can be performed in bulk scale. Exploring the properties of 2D-nps and their interactions with biological materials reveals highly interesting yet instrumental features that offer the development of novel bioanalytical approaches.     

New Uni-Resonance Approximation Technique for Reaction Rate of Higher Resonances in Activation Detectors

As a high efficiency solid sample analysis technique based on resonance ionization spectroscopy (RIS). Resonant Laser Ablation (RLA) is available. RLA combines Laser Ablation (LA) and RIS simultaneously with a single laser device. We have proposed the new dosimetry technique for a solid sample based on RLA.

We have attempted the detection of ²⁶Al (T _1/2: 7.2×10⁵yr) produced in the high purity Al irradiated by 14MeV neutrons at Fusion Neutronics Source (FNS). Japan Atomic Energy Research Institute. Some interference effects are observed in the trace element detection experiments. These interference effects interrupt the detection of ²⁶Al. In conclusion. it is difficult that ²⁶Al is recognized clearly. We have mainly discussed the origins and elimination methods of these interference effects to detect the trace elements produced by nuclear reactions.     

Reduction of Effective Sputtering Yield by Honeycomb Structures

The sputtering yield of Mo honeycomb walls was compared with the yield of fiat walls in a d.c. Ar glow discharge. Under the experimental condition where the mean energy is approximately 1 keV and the angle of incidence of primary ions strongly distributed around normal, the yield is reduced by a factor of 20 to 30. Before and after the bombardment, the surface topography of the honeycomb targets was observed by a scanning electron microscope.     

利用弹头变形识别枪击5mm钢化玻璃时序的研究

选用54式手枪、77式手枪和QSZ92式9mm手枪,分别垂直射击5mm钢化玻璃,分析弹头在贯穿玻璃后的变形和玻璃平面的痕迹特征。通过实验研究,统计并分析相关数据,得出了首发弹和非首发弹形成的弹孔痕迹以及弹头的平面痕迹特征的区别,根据弹头变形识别枪击钢化玻璃的时序。由于各种枪支不同的性能,比较多种弹头的痕迹特征,找出影响弹头痕迹特征的主要因素。     

Synthesis of graphene together with undesired CuxO nanodots on copper foils by low-pressure chemical vapor deposition

The synthesis of graphene on Cu foils has been carried out using a low-pressure chemical vapor deposition (LPCVD) process. Under certain growth conditions apart from the graphene flakes, undesired Cu_xO nanodots appear. The samples were characterized by scanning electron microscopy, atomic force microscopy, Raman spectroscopy and X-ray photoemission spectroscopy. On the basis of the results, we investigated the effect of growth parameters such as pressure, methane-to-hydrogen ratio and cooling atmosphere on the growth rate, the composition, especially the cleanliness of graphene by scanning electron microscopy in detail. It is shown that the obtained film is quite sensitive on the preparation conditions and the appearance of Cu_xO nanodots is preventable.     

Generation mechanism and prevention method of secondary molybdate phase during vitrification of PUREX wastes in liquid-fed ceramic melter

ABSTRACT

In order to develop a glass production method that inhibits formation of the Mo-bearing secondary phase, the so-called yellow phase (YP), and also to clarify its formation behavior, vitrification tests using a small-scale liquid-fed ceramic melter (LFCM) were conducted. Chemically simulated PUREX liquid waste containing Na, Mo and other fission elements was fed into a molten glass pool in the melter together with several sizes of feed glass. When the glass beads with a diameter of around 2 mm were fed, some YP was contained in the vitrified glass products at 25 wt% waste loading. While, almost no YP was detected in the glass products when glass powder with a diameter of less than 63 μm was used. The microscopic analysis of the cold-cap samples revealed that powderization of the feed glass contributed to the facilitation of Na dissolution to the feed glass in the cold-cap. This quick intake of Na to the feed glass prevented the formation of liquid Na₂MoO₄ aggregation and provided homogeneous Mo dispersion in the cold-cap with forms of alkali earth and/or rare earth molybdates. The homogeneous dispersion of Mo resulted in the fast and complete dissolution of Mo in the glass melt.